Exam III
Exam Key: Page 1
, Pages 2 & 3, Pages 4 & 5,
Page 6,
Page 7
Note: The list below was
revised on November 15, 2015. (N De Luca)
Exam Topics: The following topics
may be on the next exam. Some topics which are not listed below may
also be on the exam.
Chapter 9: Transition Metal Complexes I
Naming and writing of formulas of transition metal complexes
Naming and structures of optically active transition metal complexes.
Chapter 10:
Link to study
questions/guide (chapter 10)
- You will need to know the specific shapes and designations of the d orbitals.
- splitting patterns of d orbitals in
both octahedral and tetrahedral fields, and with tetragonal
distortions
- high spin vs. low spin - magnetic
moments of complexes
- factors
affecting ligand field strength (ligand, metal, oxidation state)
- Ligand field theory vs. crystal field
theory - how the nature of the ligand affects the MO diagram
- an understanding of the spectrochemical
series (the series will be provided)
- calculation of ligand field stabilization
energy in both octahedral and tetrahedral fields
- distortions of octahedral complexes; the Jahn-Teller
effect - what it is, when it occurs, and the strength of the effect
- square planar complexes- how the orbital splitting pattern changes as ligands along the x axis are removed
NOTE: The spectrochemical series
will be provided for you, if needed.
Copyright ©1998 Beverly
J. Volicer and Steven F. Tello, UMass Lowell. You may freely edit
these pages for use in a non-profit, educational setting. Please
include this copyright notice on all pages.